The deal will see the team work together into the future days as they prepare for next year's Africa Champions League.
The club will host each other at different intervals before the tournament. According to mtnfootball.com, Mazembe will be hosting their counterparts first in January 2013 for a fortnight.
The reverse will take place in a yet to be confirmed date.
- We have agreed that they host us in their country for two weeks where we use the time to prepare our teams for the coming assignments, Kotoko International Relations Consultant Kwame Baah-Nuakoh told the site.
Kotoko has also signed an international partnership affiliation with EPL side Sunderland.